proceeded by nucleophilic substitution with phenol 119 to deliver intermediate B via an interrupted Pummerer
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127 The 2-substituted benzofuran compound is synthesized by heterocyclic reaction of o-iodophenol using an acetylene substrate containing a terminal acetylene group. This synthetic route has focused on using palladium catalysts to variety carbon–carbon bonds and carbon-heteroatom bonds. This route is usually a flexible and straightforward technique for that synthesis of benzofuran compounds.128–one hundred thirty
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Thus, the huge array of Organic results affiliated with this scaffold has resulted while in the benzofuran ring procedure currently being regarded as a privileged construction. This has resulted in sizeable hard work currently being centered on benzofuran-dependent medicinal agents along with the growing analysis and developments are getting to be swiftly acquiring and more and more Energetic domains of investigate and therefore are prolonged to Pretty much the whole array of medicinal field.
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Proposed mechanism to the synthesis of benzofuran derivatives 28 by utilizing a palladium-based catalyst.